In regions with a cold climate, snow and ice may cover the road surface for a period. Various machinery is used to clear roads of snow. On icy surfaces, sand or grit may be used to increase the friction. For de-icing purposes, road salt is used, mostly NaCl. The salt makes the road wet, thus keeping more of the pollutants on the road surface with potential to leak into cracks in the road surface and along the road shoulder.
If let lying for an extended period of time, snow deposited along roads often becomes heavily loaded with traffic pollutants via splash and spray. The deposition rates of pollutants to the snow banks along heavily trafficked roads may be high (Table 6.4). The resulting concentrations in the snow banks may also be high but depend on the amount of snowfall (Fig. 6.2). Many heavy metals increase their solubility in the presence of ions, e. g. resulting from de-icing with NaCl. Often occurring without a coinciding heavy rainfall which would have diluted the solution, the first flush following the snow melt has high concentrations of most water-soluble pollutants. This flush mobilises considerable amounts of pollutants, often over a short period of time.
Table 6.4 Rates of deposition on snow banks for a selection of traffic pollutants from streets in two cities of Norway (B^kken, 1994b; B^kken & Tjomsland, 2001)
AADT = annual average daily traffic. PAH16 = a selection of 16 internationally agreed standard polyaromatic hydrocarbons (PAH) congeners. cPAH = potentially carcinogenic PAH congeners. HCB = hexachlorobenzene. |